2-Ethoxy-6-{(E)-[(4-methylphenyl)imino]methyl}phenol
نویسندگان
چکیده
منابع مشابه
4 - Chloro - 6 - ethoxy - 2 - ( methylthio ) pyrimidine
4,6-Dichloro-2-(methylthio)pyrimidine (3) reacts with EtONa in EtOH, at ca. 20 ◦C, for 2 h, to give exclusively 4-chloro-6-ethoxy-2-(methylthio)pyrimidine (5) in 89% yield. The latter is presented as a useful multifunctionalised pyrimidine scaffold.
متن کامل2-[(E)-(4-Fluorobenzyl)iminomethyl]-6-methoxyphenol
In the title Schiff base, C(15)H(14)FNO(2), the dihedral angle between the benzene rings is 53.32 (8)°. In the crystal, mol-ecules related by a twofold rotation axis are linked by pairs of C-H⋯O hydrogen bonds into dimers with R(2) (2)(18) ring motifs. An intra-molecular O-H⋯N hydrogen bond is also observed.
متن کامل(E)-2-[(4-Iodophenyl)iminomethyl]-6-methylphenol
The title compound, C(14)H(12)INO, adopts the phenol-imine tautomeric form. The dihedral angle between the aromatic rings is 20.6 (3)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond while in the crystal, weak inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into a zigzag chain parallel to the b axis.
متن کامل2-[(E)-(4-Methylphenyl)iminomethyl]-6-(morpholin-4-ylmethyl)phenol
In the title compound, C(19)H(22)N(2)O(2), the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q(T), θ and ϕ of 0.5642 (18) Å, 177.32 (17) and ϕ = 10 (4)°, respectively. The two benzene rings make a dihedral angle of 42.67 (8)° with each other. An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular conformation. Aromatic C-H⋯π inter...
متن کامل(E)-4-Allyl-2-[(2-hydroxyphenyl)iminiomethyl]-6-methoxyphenolate
The title compound, C(17)H(17)NO(3), crystallizes in a zwitterionic form with cationic iminium and anionic enolate groups. The zwitterion exists in a trans configuration about the C=N bond. The dihedral angle between the two benzene rings is 13.42 (7)°. The meth-oxy group is almost coplanar [C-O-C-C = 2.1 (2)°] with the attached ring whereas the allyl unit is oriented at a dihedral angle of 67....
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812024798